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Iron-Catalyzed Synthesis of Fused Aromatic Compounds via C–H Bond Activation, 2014 Springer Theses Series

Langue : Anglais

Auteur :

Couverture de l’ouvrage Iron-Catalyzed Synthesis of Fused Aromatic Compounds via C–H Bond Activation
Iron catalysts in organic synthesis are strongly in demand because iron is non-toxic, inexpensive and the most abundant transition metal in the earth, although their use is still limited compared with that of rare, precious metals such as palladium, ruthenium and rhodium. This thesis describes the first practical example of iron catalysis in the carbon?hydrogen bond activation reaction to synthesized fused aromatic ring compounds. By using a unique combination of iron catalyst and dichloride oxidant, various kind of naphthalene and phenanthrene derivatives were synthesized via annulation reaction with alkynes including direct C?H bond activation process. This achievement opens the new possibility of low-valent iron catalysis and expands synthetic methods for a sustainable society.
General Introduction.- Iron-Catalyzed Naphthalene Synthesis from Alkyne and Grignard Reagent.- Iron-Catalyzed Phenanthrene Synthesis from Alkyne and Grignard Reagent.- Iron-Catalyzed Phenanthrene Synthesis from Alkyne and Aryl Bromide Mediated by Metallic Magnesium.- Summary and Perspectives.

Nominated by The University of Tokyo as an outstanding Ph.D. thesis

Provides examples of C-H bond activation which has attracted attention as an important chemical reaction in organic chemistry

Shows researchers how to develop a new reactivity of iron that is not only a simple alternative to rare metals

Includes supplementary material: sn.pub/extras

Date de parution :

Ouvrage de 74 p.

15.5x23.5 cm

Disponible chez l'éditeur (délai d'approvisionnement : 15 jours).

105,49 €

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Date de parution :

Ouvrage de 74 p.

15.5x23.5 cm

Disponible chez l'éditeur (délai d'approvisionnement : 15 jours).

105,49 €

Ajouter au panier

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