Lavoisier S.A.S.
14 rue de Provigny
94236 Cachan cedex
FRANCE

Heures d'ouverture 08h30-12h30/13h30-17h30
Tél.: +33 (0)1 47 40 67 00
Fax: +33 (0)1 47 40 67 02


Url canonique : www.lavoisier.fr/livre/chimie/electrochemical-impedance-spectroscopy-2nd-ed/orazem/descriptif_3631627
Url courte ou permalien : www.lavoisier.fr/livre/notice.asp?ouvrage=3631627

Electrochemical Impedance Spectroscopy (2nd Ed., 2nd Edition) The ECS Series of Texts and Monographs Series

Langue : Anglais

Auteurs :

Couverture de l’ouvrage Electrochemical Impedance Spectroscopy
Provides fundamentals needed to apply impedance spectroscopy to a broad range of applications with emphasis on obtaining physically meaningful insights from measurements. 
  • Emphasizes fundamentals applicable to a broad range of applications including corrosion, biomedical devices, semiconductors, batteries, fuel cells, coatings, analytical chemistry, electrocatalysis, materials, and sensors 
  • Provides illustrative examples throughout the text that show how the principles are applied to common impedance problems
  • New Edition has improved pedagogy, with more than twice the number of examples
  • New Edition has more in-depth treatment of background material needed to understand impedance spectroscopy, including electrochemistry, complex variables, and differential equations 
  • New Edition includes expanded treatment of the influence of mass transport and kinetics and reflects recent advances in understanding frequency dispersion and constant-phase elements
- Preface to the Second Edition
. Preface to the First Edition
. Acknowledgments
. The Blind Men and the Elephant
. A Brief Introduction to Impedance Spectroscopy
. History of Impedance Spectroscop

I - Background

1. Complex Variables
. 1.1 Why Imaginary Numbers?
. 1.2 Terminology
. 1.3 Operations Involving Complex Variables
. 1.4 Elementary Functions of Complex Variables
. Problems

2. Differential Equations
. 2.1 Linear First–Order Differential Equations
. 2.2 Homogeneous Linear Second–Order Differential Equations
. 2.3 Nonhomogeneous Linear Second–Order Differential Equations
. 2.4 Chain Rule for Coordinate Transformations
. 2.5 Partial Differential Equations by Similarity Transformations
. 2.6 Differential Equations with Complex Variables
. Problems

3. Statistics
. 3.1 Definitions
. 3.2 Error Propagation
. 3.3 Hypothesis Tests
. Problems

4. Electrical Circuits
. 4.1 Passive Electrical Circuits
. 4.2 Fundamental Relationships
. 4.3 Nested Circuits
. 4.4 Mathematical Equivalence of Circuits
. 4.5 Graphical Representation of Circuit Response
. Problems

5. Electrochemistry
. 5.1 Resistors and Electrochemical Cells
. 5.2 Polarization Behavior for Electrochemical Systems
. 5.3 Definitions of Potential
. 5.4 Rate Expressions
. 5.5 Transport Processes
. 5.6 Potential Contributions
. 5.7 Capacitance Contributions
. 5.8 Further Reading
. Problems

6. Electrochemical Instrumentation
. 6.1 The Ideal Operational Amplifier
. 6.2 Elements of Electrochemical Instrumentation
. 6.3 Electrochemical Interface
. Problems

II - Experimental Considerations

7. Experimental Methods
. 7.1 Steady–State Polarization Curves
. 7.2 Transient Response to a Potential Step
. 7.3 Analysis in Frequency Domain
. 7.4 Comparison of Measurement Techniques
. 7.5 Specialized Techniques
. Problems

8. Experimental Design
. 8.1 Cell Design
. 8.2 Experimental Considerations
. 8.3 Instrumentation Parameters
. Problems

III - Process Models

9. Equivalent Circuit Analogs
. 9.1 General Approach
. 9.2 Current Addition
. 9.3 Potential Addition
. Problems

10 - Kinetic Models
. 10.1 General Mathematical Framework
. 10.2 Electrochemical Reactions
. 10.3 Multiple Independent Electrochemical Reactions
. 10.4 Coupled Electrochemical Reactions
. 10.5 Electrochemical and Heterogeneous Chemical Reactions
. Problems

11. Diffusion Impedance
. 11.1 Uniformly Accessible Electrode
. 11.2 Porous Film
. 11.3 Rotating Disk
. 11.4 Submerged Impinging Jet
. 11.5 Rotating Cylinders
. 11.6 Electrode Coated by a Porous Film
. 11.7 Impedance with Homogeneous Chemical Reactions
. 11.8 Dynamic Surface Films
. Problems

12. Impedance of Materials
. 12.1 Electrical Properties of Materials
. 12.2 Dielectric Response in Homogeneous Media
. 12.3 Cole–Cole Relaxation
. 12.4 Geometric Capacitance
. 12.5 Dielectric Response of Insulating Non–Homogenous Media
. 12.6 Mott–Schottky Analysis
. Problems

13. Time–Constant Dispersion
. 13.1 Transmission Line Models
. 13.2 Geometry Induced Current and Potential Distributions
. 13.3 Electrode Surface Property Distributions
. 13.4 Characteristic Dimension for Frequency Dispersion
. 13.5 Convective Diffusion Impedance at Small Electrodes
. 13.6 Coupled Charging and Faradaic Currents
. 13.7 Exponential Resistivity Distributions
. Problems

14. Constant Phase Elements
. 14.1 Mathematical Formulation for a CPE
. 14.2 When is a Time Constant Distribution a CPE?
. 14.3 Origin of Distributions Resulting in a CPE
. 14.4 Approaches for Extracting Physical Properties
. 14.5 Limitations to the Use of the CPE
. Problems

15. Generalized Transfer Functions
. 15.1 Multi–Input/Multi–Output Systems
. 15.2 Transfer Functions Involving Exclusively Electrical Quantities
. 15.3 Transfer Functions Involving Nonelectrical Quantities
. Problems

16. Electrohydrodynamic Impedance
. 16.1 Hydrodynamic Transfer Function
. 16.2 Mass–Transport Transfer Function
. 16.3 Kinetic Transfer Function for Simple Electrochemical Reactions
. 16.4 Interface with a 2–D or 3–D Insulating Phase
. Problems

IV. Interpretation Strategies

17 Methods for Representing Impedance
. 17.1 Impedance Format
. 17.2 Admittance Format
. 17.3 Complex–Capacitance Format
. 17.4 Effective Capacitance
. Problems

18. Graphical Methods
. 18.1 Based on Nyquist Plots
. 18.2 Based on Bode Plots
. 18.3 Based on Imaginary Part of the Impedance
. 18.4 Based on Dimensionless Frequency
. 18.5 System Specific Applications
. 18.6 Overview
. Problems

19. Complex Nonlinear Regression
. 19.1 Concept
. 19.2 Objective Functions
. 19.3 Formalism of Regression Strategies
. 19.4 Regression Strategies for Nonlinear Problems
. 19.5 Influence of Data Quality on Regression
. 19.6 Initial Estimates for Regression
. 19.7 Regression Statistics
. Problems

20. Assessing Regression Quality
. 20.1 Methods to Assess Regression Quality
. 20.2 Application of Regression Concepts
. Problems

V - Statistical Analysis

21. Error Structure of Impedance Measurements

. 21.1 Error Contributions
. 21.2 Stochastic Errors in Impedance Measurements
. 21.3 Bias Errors
. 21.4 Incorporation of Error Structure
. 21.5 Measurement Models for Error Identification
. Problems

22. The Kramers–Kronig Relations
. 22.1 Methods for Application
. 22.2 Mathematical Origin
. 22.3 The Kramers–Kronig in an Expectation Sense
. Problems

VI - Overview

23. An Integrated Approach to Impedance Spectroscopy
. 23.1 Flowcharts for Regression Analysis
. 23.2 Integration of Measurements, Error Analysis, and Model
. 23.3 Application
. Problems

VII - Reference Material

A - Complex Integrals
. A.1 Definition of Terms
. A.2 Cauchy–Riemann Conditions
. A.3 Complex Integration
. Problems
B - Tables of Reference Material
C - List of Examples
. List of Symbols
. References
. Index
Mark E. Orazem is a Distinguished Professor of Chemical Engineering at the University of Florida, adjunct professor at the Beijing University of Chemical Technology, a Fellow of the Electrochemical Society, past President of the International Society of Electrochemistry, and recipient of the 2012 ECS Linford Award for Outstanding Teaching

Bernard Tribollet is Director of Research Emeritus at the Laboratory for Interfaces and Electrochemical Systems (LISE) at the University of Pierre and Marie Curie and adjunct professor at the Beijing University of Chemical Technology. He instructs an annual short course at his university on impedance spectroscopy.

Date de parution :

Ouvrage de 712 p.

18.4x26 cm

Disponible chez l'éditeur (délai d'approvisionnement : 12 jours).

Prix indicatif 140,78 €

Ajouter au panier

Thème d’Electrochemical Impedance Spectroscopy :

En continuant à naviguer, vous autorisez Lavoisier à déposer des cookies à des fins de mesure d'audience. Pour en savoir plus et paramétrer les cookies, rendez-vous sur la page Confidentialité & Sécurité.
FERMER