Chemistry of Organo-hybrids Synthesis and Characterization of Functional Nano-Objects

This book provides readers with a one-stop entry into the chemistry of varied hybrids and applications, from a molecular synthetic standpoint

? Describes introduction and effect of organic structures on specific support components (carbon-based materials, proteins, metals, and polymers).
? Chapters cover hot topics including nanodiamonds, nanocrystals, metal-organic frameworks, peptide bioconjugates, and chemoselective protein modification
? Describes analytical techniques, with pros and cons, to validate synthetic strategies
? Edited by internationally-recognized chemists from different backgrounds (synthetic polymer chemistry, inorganic surfaces and particles, and synthetic organic chemistry) to pull together diverse perspectives and approaches

Preface vii

Contributors ix

1COVALENT ORGANIC FUNCTIONALIZATION ANDCHARACTERIZATION OF CARBON NANOTUBES 1
Cécilia Ménard-Moyon

2FUNCTIONALIZED GRAPHENES 36
Iban Azcarate, David Lachkar, Emmanuel Lacôte,Jennifer Lesage de la Haye, and Anne-Laure Vallet

3NANODIAMONDS: EMERGENCE OF FUNCTIONALIZEDDIAMONDOIDS AND THEIR UNIQUE APPLICATIONS 69
Maria A. Gunawan, Paul Kahl, Didier Poinsot, Bruno Domenichini,Peter R. Schreiner, Andrey A. Fokin, and Jean-Cyrille Hierso

4TITANIA-BASED HYBRID MATERIALS: FROM MOLECULARPRECURSORS TO THE CONTROLLED DESIGN OFHIERARCHICAL HYBRID MATERIALS 114
Laurence Rozes, Loïc D’Arras, Chloé Hoffman, François Potier,Niki Halttunen, and Lionel Nicole

5FUNCTIONALIZATION OF ZIRCONIUM OXIDE SURFACES 168
Marc Petit and Julien Monot

6FUNCTIONAL METAL–ORGANIC FRAMEWORKS:SYNTHESIS AND REACTIVITY 200
Flavien L. Morel, Xiaoying Xu, Marco Ranocchiari, andJeroen A. van Bokhoven

7SURFACE CHEMISTRY OF COLLOIDAL SEMICONDUCTORNANOCRYSTALS: ORGANIC, INORGANIC, AND HYBRID 233
Richard Brutchey, Zeger Hens, and Maksym V. Kovalenko

8COVALENT ORGANIC FUNCTIONALIZATION OFNUCLEIC ACIDS 272
Michel Arthur and Mélanie Etheve-Quelquejeu

9CHEMOSELECTIVE PROTEIN MODIFICATIONS: METHODSAND APPLICATIONS FOR THE FUNCTIONALIZATION OFVIRAL CAPSIDS 299
Divya Agrawal and Christian P. R. Hackenberger

10CYCLODEXTRINS–METAL HYBRIDS 349
Maxime Guitet, Mickaël Ménand, and Matthieu Sollogoub

11POST-FUNCTIONALIZATION OF POLYMERS VIAORTHOGONAL LIGATION CHEMISTRY 395
Anja S. Goldmann, M. Glassner, Andrew J. Inglis, and ChristopherBarner-Kowollik

12POLYMER–PROTEIN/PEPTIDE BIOCONJUGATES 466
Paul Wilson, Julien Nicolas, and David M. Haddleton

13HYBRID MATERIALS BUILT FROM (PHOSPHORUS)DENDRIMERS 503
Anne-Marie Caminade, Beatrice Delavaux-Nicot, and Jean-Pierre Majoral

Index

Bernadette Charleux is a Professor at the Claude Bernard Lyon 1 University, and a Senior Member of the Institut Universitaire de France.

Christophe Copéret (CCH) is a Professor in the Department of Chemistry (Institute of Inorganic chemistry) at ETH Zürich.