Atomic structure and periodicity (Tutorial chemistry text, vol. 9)

This book presents basic atomic theory as given in first and second year courses at university. It demonstrates that the structure of the Periodic Table as we know it is based on sound principles. Throughout the book, theoretical concepts are presented, along with the experimental evidence for them. Foundations are laid in the introductory chapter, which deals with fundamental particles, electromagnetic radiation and Heisenberg's uncertainty principle. Atomic orbitals are then described, using a minimum of mathematics, followed by a discussion of the electron configurations of the elements. Further chapters reveal the relationships between the electronic configurations of the elements and some properties of their atoms, and the variations in the properties of their fluorides and oxides across the periods and down the groups of the Periodic Table.

Atomic particles, photons and the quantization of electron energies, Heisenberg's uncertainty principle. Atomic orbitals. The electron configurations of atoms, the periodic classification of the elements. Periodicity / some atomic properties, relativistic effects, Valencies and oxidation states, standard enthalpies of atomization of the elements, fluorides and oxides, elements and aqueous solutions, standard reduction potentials. Solutions to problems. Index.