Asymmetric Organocatalysis From Biomimetic Concepts to Applications in Asymmetric Synthesis
Auteurs : Berkessel Albrecht, Gröger Harald
Préfacier : MacMillan David
General Mechanistic Considerations
Nucleophilic Substitution at Aliphatic Carbon
Nucleophilic Addition to Electron-deficient C=C Double Bonds
Nucleophilic Addition to C=N Double Bonds
Nucleophilic Addition to C=O Double Bonds
Nucleophilic Addition to Unsaturated Nitrogen
Cycloaddition Reactions
Protonation of Enolates and Tautomerization of Enols
Oxidation
Reduction of Carbonyl Compounds
Kinetic Resolution of Racemic Alcohols and Amines
Desymmetrization and Kinetic Resolution of Anhydrides
Large-Scale Applications
Appendix: Tabular Survey of Organo-Catalysts, Synthesis and Application
Harald Groger is currently working at the Degussa AG. His research is focussed on enzymatic reactions and biocatalysis.
Date de parution : 03-2005
Ouvrage de 454 p.
17.8x24.6 cm
Thème d’Asymmetric Organocatalysis :
Mots-clés :
synthesis; catalysis; everincreasing importance; organic; asymmetric; industrial; academic; environment; metalbased; methods; extremes; weight; lowmolecular; transformations; enantioselective; third; highly; catalysts; use; tool; book; experienced